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Articles [14138]
Doctoral Dissertations [79]
Other [501]
Books [2580]
Conference papers [551]
Diploma Theses [99]
Reports [307]
Books Chapters [2812]

OPEN Repository

Welcome to OPEN - the Repository of Open Scientific Publications, run by the Interdisciplinary Centre for Mathematical and Computational Modelling, University of Warsaw, previously operating as the CeON Repository. The Repository enables Polish researchers from all fields to openly share their articles, books, conference materials, reports, doctoral theses, and other scientific texts.

Publications in the Repository are indexed by the most important search engines and aggregators and downloaded by users worldwide. We invite you to create an account, deposit your publications, and use the resources of the Repository.

22936 archived items

Institutional Communities

Police Academy in Szczytno [75]
Centrum Badań Molekularnych i Makromolekularnych PAN [0]
ICM UW [101]
Instytut Badań Literackich PAN [186]
Instytut Chemii Fizycznej PAN [181]
Instytut Chemii Organicznej PAN [132]
Jerzy Haber Institute of Catalysis and Surface Chemistry PAS [21]
Instytut Paleobiologii PAN [2]
Katedra Arabistyki i Islamistyki WO UW [131]
Katedra Języków i Kultur Afryki WO UW [21]
OBM UW [131]
Uczelnia Łazarskiego [126]
Uniwersytet Przyrodniczy w Poznaniu [92]
Wydawnictwo Naukowe PTG [284]
Wydział Lingwistyki Stosowanej UW [48]
Wydział Polonistyki UW [339]

Recent Submissions

Item

Propargylation of CoQ0 through the Redox Chain Reaction

(American Chemical Society, 2022-01) Pawlowski, Robert; Stodulski, Maciej; Mlynarski, Jacek; Institute of Organic Chemistry, Polish Academy of Sciences

An efficient catalytic propargylation of CoQ0 is described by employing the cooperative effect of Sc(OTf)3 and Hantzsch ester. It is suggested to work through the redox chain reaction, which involves hydroquinone and dimeric propargylic moiety intermediates. A broad range of propargylic alcohols can be converted into the appropriate derivatives of CoQ0 containing triple bonds in good to excellent yields. The mechanism of the given transformation is also discussed.

Item

Bioinspired Cobalt-Catalysis Enables Generation of Nucleophilic Radicals from Oxetanes

(American Chemical Society, 2022-03-25) Potrząsaj, Aleksandra; Ociepa, Michał; Chaładaj, Wojciech; Gryko, Dorota; Institute of Organic Chemistry, Polish Academy of Sciences

Oxetanes are valuable building blocks due to their well-explored propensity to undergo ring-opening reactions with nucleophiles. However, their application as precursors of radical species is still elusive. Herein, we present a bioinspired cobalt catalysis-based strategy to access unprecedented modes of radical reactivity via oxetane ring-opening. This powerful approach gives access to nucleophilic radicals that engage in reactions with SOMOphiles and low-valent transition metals. Importantly, the regioselectivity of these processes complements known methodologies.