A BZ Assemblage Working for a Day

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dc.contributor.authorMuzika, František
dc.contributor.authorGórecki, Jerzy
dc.contributor.organizationInstitute of Physical Chemistry Polish Academy of Sciencesen
dc.date.accessioned2022-11-24T12:56:26Z
dc.date.available2022-11-24T12:56:26Z
dc.date.issued2021-12-15
dc.description.abstractOur work is focused on the experimental observation of Bielousov-Zhabotinsky reaction oscillations in ferroin loaded Dowex 50w beads in a batch reactor open to the atmosphere. We investigated the conditions for the maximum oscillation lifetime and the change of wave regimes as the answer to the applied potential. The catalyst-free solution in the batch reactor is a mixture of concentrated sulphuric acid, NaBrO3, and different ratios of malonic acid and 1,4 cyclohexanedione. We are using three types of cation Dowex 50w beads, namely type x2, x8, which differ by their level of crosslinking and cation exchange capacity. Their mesh size is 16-50 and 50-100. We investigate the influence of such parameters as the distance between a bead and the electrode and the value of electrode potential on the oscillations. Moreover, we study the character of oscillations in the function of the number of adjacent beads and the layout of the beads.The reduction of formation of CO2 bubbles has been achieved by choice of Dowex beads type, solution composition, and usage of acetone.We report oscillations with stable amplitude and varying period and lifetime over 19 hours and oscillations with decreasing amplitude with a lifetime of 10 hours. The investigated media and beads type seem to be promising candidates for experimental realization of chemical computers based on interacting oscillators.en
dc.description.sponsorshipThis publication is part of a project that has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie Grant Agreement No. 847413. Scientific work published as part of an international co-financed project founded from the programme of the Minister of Science and Higher Education entitled “PMW” in the years 2020–2024; Agreement No. 5005/H2020-MSCA-COFUND/2019/2.en
dc.identifier.citationMuzika, F., Górecki, J. (2021). A BZ Assemblage Working for a Day. In: Ž. Čupić and S. Anić (Eds.), PHYSICAL CHEMISTRY 2021. 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry Proceedings. Volume I (pp. 201-207). Te Society of Physical Chemists of Serbiaen
dc.identifier.isbn978-86-82475-40-8
dc.identifier.isbn978-86-82475-38-5
dc.identifier.urihttps://open.icm.edu.pl/handle/123456789/21892
dc.language.isoen
dc.publisherSociety of Physical Chemists of Serbiaen
dc.relationthe European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie Grant Agreement No. 847413; Agreement No. 5005/H2020-MSCA-COFUND/2019/2en
dc.rightsUznanie autorstwa-Użycie niekomercyjne-Bez utworów zależnych 3.0 Polska*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/pl/*
dc.subjectBelousov–Zhabotinskyen
dc.subject1-4-Cyclohexanedioneen
dc.subjecttravelling waveen
dc.subjectpolymer beadsen
dc.subjectDowexen
dc.subjectelectric potentialen
dc.titleA BZ Assemblage Working for a Dayen
dc.typeconferencePaperen
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