Vitamin B12 and a metal–organic framework enable the photocatalytic generation of alkyl radicals

Thumbnail Image
d3cc02941g(1).pdf (750.06 KB)
Authors
Dworakowski, Krzysztof R.
Chołuj, Artur
Chmielewski, Michał J.
Gryko, Dorota
Date
2023
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
License
Creative Commons License
Creative Commons Attribution-NonCommercial 3.0 Poland License
Abstract
A versatile Co-catalyst-vitamin B12 (cobalamin)-can be photochemically reduced to its catalytically active Co(I) formunder visible light irradiation, in the presence of MIL-125-NH2(Ti) as a photocatalyst and utilized for the generation of alkyl radicals. The prior reduction of cobalamin to the Co(II) form is not required in this method.
Description
Citation
Chem. Commun., 2023 ; https://doi.org/10.1039/D3CC02941G
URI
https://open.icm.edu.pl/handle/123456789/22859
Belongs to collection
Artykuły IChO PAN