Vitamin B12 and a metal–organic framework enable the photocatalytic generation of alkyl radicals

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dc.contributor.authorDworakowski, Krzysztof R.
dc.contributor.authorChołuj, Artur
dc.contributor.authorChmielewski, Michał J.
dc.contributor.authorGryko, Dorota
dc.contributor.organizationInstitute of Organic Chemistry, Polish Academy of Sciencesen
dc.contributor.organizationFaculty of Chemistry, Biological and Chemical Research Centre, University of Warsawen
dc.date.accessioned2023-09-05T15:02:13Z
dc.date.available2023-09-05T15:02:13Z
dc.date.issued2023
dc.description.abstractA versatile Co-catalyst-vitamin B12 (cobalamin)-can be photochemically reduced to its catalytically active Co(I) formunder visible light irradiation, in the presence of MIL-125-NH2(Ti) as a photocatalyst and utilized for the generation of alkyl radicals. The prior reduction of cobalamin to the Co(II) form is not required in this method.en
dc.description.sponsorshipNational Science Centre, Poland, OPUS UMO-2020/39/I/ST4/00405, OPUS UMO-2017/27/B/ST5/00941
dc.identifier.citationChem. Commun., 2023 ; https://doi.org/10.1039/D3CC02941Gen
dc.identifier.doi10.1039/D3CC02941G
dc.identifier.issn1359-7345
dc.identifier.issn1364-548x
dc.identifier.urihttps://open.icm.edu.pl/handle/123456789/22859
dc.language.isoen
dc.publisherRoyal Society of Chemistryen
dc.rightsUznanie autorstwa-Użycie niekomercyjne 3.0 Polska*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/pl/*
dc.titleVitamin B12 and a metal–organic framework enable the photocatalytic generation of alkyl radicalsen
dc.typearticleen
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