Chlorine in an Organic Molecule, a Universal Promoter—Workhorse—Of Reactions
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| dc.contributor.author | Mąkosza, Mieczysław | |
|---|---|---|
| dc.contributor.author | Fedoryński, Michał | |
| dc.contributor.editor | Dembinski, Roman | |
| dc.contributor.organization | Institute of Organic Chemistry, Polish Academy of Sciences | |
| dc.contributor.organization | Faculty of Chemistry, Warsaw University of Technology | |
| dc.date.accessioned | 2024-09-18T14:23:52Z | |
| dc.date.available | 2024-09-18T14:23:52Z | |
| dc.date.issued | 2023 | |
| dc.description.abstract | Due to the electronic configuration of the atom and charge of the nucleus, the chlorine in organic molecules can exert a variety of effects. It can depart as a chloride anion in the process of substitution and elimination, facilitates the abstraction of protons and stabilizes generated carbanions, exerts moderate stabilizing effect of carbenes, carbocations and radicals. There are frequent cases where chlorine substituent promotes more than one transformation. These rich effects of chlorine substituent will be illustrated by examples of our work. | en |
| dc.identifier.citation | Molecules 2023, 28, 7957 ; https://doi.org/10.3390/molecules28247957 | |
| dc.identifier.doi | 10.3390/molecules28247957 | |
| dc.identifier.issn | 1420-3049 | |
| dc.identifier.uri | https://open.icm.edu.pl/handle/123456789/24859 | |
| dc.language.iso | en | |
| dc.publisher | MDPI | |
| dc.rights | Uznanie autorstwa 4.0 Międzynarodowe | en |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
| dc.source | Molecules | |
| dc.subject | phase transfer catalysis | en |
| dc.subject | γ-halocarbanions | en |
| dc.subject | dichlorocarbene | en |
| dc.subject | vicarious nucleophilic substitution | en |
| dc.subject | nucleophilic substitution of chlorine | en |
| dc.subject | base induced β-elimination | en |
| dc.subject | α-halocarbanions | en |
| dc.subject | Darzens reaction | en |
| dc.subject | chlorine as electrophilic center | en |
| dc.title | Chlorine in an Organic Molecule, a Universal Promoter—Workhorse—Of Reactions | en |
| dc.type | article | |
| dc.type.version | publishedVersion | |
| person.identifier.orcid | Mąkosza, Mieczysław [0000-0001-9091-7792] |
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