NHC-Cu Three-Coordinate Complex as a Promising Photocatalyst for Energy and Electron Transfer Reactions

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Authors
Grudzień, Krzysztof
Szeptuch, Zuzanna
Kubiszewski, Hubert
Chaładaj, Wojciech ORCID logo 0000-0001-8143-3788
Rybicka-Jasińska, Katarzyna ORCID logo 0000-0002-9018-7846
Date
2024
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society
License
Creative Commons License
Creative Commons Attribution 4.0 International License
Abstract
Herein, we describe a simple three-coordinate complex of Cu(I) with an NHC and 1,10-phenanthroline ligands as an effective photocatalyst for energy (e.g., olefin E/Z isomerization) and electron transfer (e.g., aryl halide dehalogenation) reactions under blue-light irradiation. This complex can be obtained in a one-pot procedure starting from commercially available reagents and green solvents (EtOH, water). We hereby present a study of its activity and mechanistic insight into its mode of operation.
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Citation
J. Org. Chem. 2024, 89, 8546−8550 ; https://doi.org/10.1021/acs.joc.4c00450
URI
https://open.icm.edu.pl/handle/123456789/25093
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