NHC-Cu Three-Coordinate Complex as a Promising Photocatalyst for Energy and Electron Transfer Reactions

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dc.contributor.authorGrudzień, Krzysztof
dc.contributor.authorSzeptuch, Zuzanna
dc.contributor.authorKubiszewski, Hubert
dc.contributor.authorChaładaj, Wojciech
dc.contributor.authorRybicka-Jasińska, Katarzyna
dc.contributor.organizationInstitute of Organic Chemistry, Polish Academy of Sciences
dc.date.accessioned2024-11-18T13:36:51Z
dc.date.available2024-11-18T13:36:51Z
dc.date.issued2024
dc.description.abstractHerein, we describe a simple three-coordinate complex of Cu(I) with an NHC and 1,10-phenanthroline ligands as an effective photocatalyst for energy (e.g., olefin E/Z isomerization) and electron transfer (e.g., aryl halide dehalogenation) reactions under blue-light irradiation. This complex can be obtained in a one-pot procedure starting from commercially available reagents and green solvents (EtOH, water). We hereby present a study of its activity and mechanistic insight into its mode of operation.en
dc.description.sponsorshipNational Science Center (PL) SONATA UMO-2020/39/D/ST4/01510; Wroclaw Centre for Networking and Supercomputing, grant no. 518.
dc.identifier.citationJ. Org. Chem. 2024, 89, 8546−8550 ; https://doi.org/10.1021/acs.joc.4c00450
dc.identifier.doi10.1021/acs.joc.4c00450
dc.identifier.issn0022-3263
dc.identifier.issn1520-6904
dc.identifier.urihttps://open.icm.edu.pl/handle/123456789/25093
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.rightsUznanie autorstwa 4.0 Międzynarodoween
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.sourceJournal of Organic Chemistry
dc.titleNHC-Cu Three-Coordinate Complex as a Promising Photocatalyst for Energy and Electron Transfer Reactionsen
dc.typearticle
dc.type.versionpublishedVersion
person.identifier.orcidChaładaj, Wojciech [0000-0001-8143-3788]
person.identifier.orcidRybicka-Jasińska, Katarzyna [0000-0002-9018-7846]
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