V-shaped donor–acceptor organic emitters. A new approach towards efficient TADF OLED devices

Abstract
We report the synthesis and characterization of a series of donor–acceptor TADF emitters with a new architecture, where the donor moiety and the dibenzazepine-based acceptor moiety are separated by a phenylene linker in a V-shaped spatial arrangement. Such spatial separation and electronic decoupling between the donor and the acceptor moieties leads to low singlet-triplet energy gaps and favors efficient exciton up-conversion.
Description
Citation
Chem. Commun., 2023, 59, 2815–2818 ; https://doi.org/10.1039/D2CC06978D
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