Phase Transitions and Electrochemical Properties of Ionic Liquids and Ionic Liquid-Solvent Mixtures

Full item record

dc.contributor.authorCruz, Carolina
dc.contributor.authorCiach, Alina
dc.contributor.organizationInstitute of Physical Chemistry, Polish Academy of Sciencesen
dc.date.accessioned2022-03-15T10:26:53Z
dc.date.available2022-03-15T10:26:53Z
dc.date.issued2021-06-16
dc.description.abstractRecent advances in studies of ionic liquids (IL) and ionic liquid–solvent mixtures are reviewed. Selected experimental, simulation, and theoretical results for electrochemical, thermodynamical, and structural properties of IL and IL-solvent mixtures are described. Special attention is paid to phenomena that are not predicted by the classical theories of the electrical double layer or disagree strongly with these theories. We focus on structural properties, especially on distribution of ions near electrodes, on electrical double layer capacitance, on effects of confinement, including decay length of a dissjoining pressure between confinig plates, and on demixing phase transition. In particular, effects of the demixing phase transition on electrochemical properties of ionic liquid–solvent mixtures for different degrees of confinement are presented.en
dc.description.sponsorshipMarie Skłodowska-Curie grant agreement No. 711859 to C.C. Ministry of Science and Higher Education of Poland for the project No. 734276 , agreement No. 3854/H2020/17/2018/2.
dc.identifier.citationCruz, Carolina, and Alina Ciach. "Phase transitions and electrochemical properties of ionic liquids and ionic liquid—Solvent mixtures." Molecules 26, no. 12 (2021): 3668. https://doi.org/10.3390/molecules26123668en
dc.identifier.doi10.3390/molecules26123668
dc.identifier.issn1420-3049
dc.identifier.urihttps://open.icm.edu.pl/handle/123456789/21143
dc.language.isoen
dc.publisherMDPIen
dc.relationH2020 - European Commissionen
dc.rightsUznanie autorstwa 4.0 Międzynarodowe*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectionic liquidsen
dc.subjectionic liquid-solvent mixturesen
dc.subjectdemixing phase transitionen
dc.subjecteffects of confinement in ionic systemsen
dc.subjectdifferential capacitanceen
dc.subjectelectrical double layeren
dc.titlePhase Transitions and Electrochemical Properties of Ionic Liquids and Ionic Liquid-Solvent Mixturesen
dc.typearticleen
Files for this record
Original bundle
Now showing 1 - 1 of 1
Name: molecules-26-03668.pdf
Size: 5.87 MB
Format: Adobe Portable Document Format
Description: Main article
License files
Name: license.txt
Size: 228 B
Format: Item-specific license agreed upon to submission
Description: