Hydrogen-bonded supramolecular assemblies of folic acid with simple hexoses

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dc.contributor.authorCeborska, Magdalena
dc.contributor.authorDąbrowa, Kajetan
dc.contributor.authorCędrowski, Jakub
dc.contributor.authorZimnicka, Magdalena
dc.contributor.organizationInstitute of Physical Chemistry, Polish Academy of Sciencesen
dc.contributor.organizationInstitute of Organic Chemistry, Polish Academy of Sciencesen
dc.contributor.organizationFaculty of Chemistry, University of Warsawen
dc.date.accessioned2022-08-31T13:30:32Z
dc.date.available2022-08-31T13:30:32Z
dc.date.issued2022
dc.description.abstractSimple D-hexoses such as D-glucose, D-mannose, and D-galactose were found to form supramolecular complexes with folic acid (FA) in phosphate-buffered saline solution (PBS, pH 7.4) and in the gas phase. Pterin subunit of FA was found to be essential for the molecular assembly with hexoses, whereas PABA (p-amino benzoic acid) and GLN (glutamic acid) subunits of FA have virtually no effect on assembly formation. Experimental measurements along with DFT theoretical calculations reveal that hexose-FA assemblies are stabilized by three complementary hydrogen bonds between pterin subunit of FA and 3,4,6-trihydroxyl moiety of hexose.en
dc.identifier.citationCeborska, M., Dąbrowa, K.,Cędrowski, J., Zimnicka, M. (2022). Hydrogen-bonded supramolecular assemblies of folic acid with simple hexoses. Journal of Molecular Structure: 1250, Part 3, 131904. https://doi.org/10.1016/j.molstruc.2021.131904en
dc.identifier.doi10.1016/j.molstruc.2021.131904
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.urihttps://open.icm.edu.pl/handle/123456789/21596
dc.language.isoen
dc.publisherElsevieren
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Międzynarodowe*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectfolic aciden
dc.subjectmonosaccharidesen
dc.subjecthydrogen bonded associatesen
dc.subjectsupramolecular chemistryen
dc.titleHydrogen-bonded supramolecular assemblies of folic acid with simple hexosesen
dc.typearticleen
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