Magnetic Antiaromaticity─Paratropicity─Does Not Necessarily Imply Instability

Foroutan-Nejad, Cina

Magnetic Antiaromaticity─Paratropicity─Does Not Necessarily Imply Instability

dc.contributor.author	Foroutan-Nejad, Cina
dc.contributor.organization	Institute of Organic Chemistry, Polish Academy of Sciences	en
dc.date.accessioned	2023-10-11T15:02:38Z
dc.date.available	2023-10-11T15:02:38Z
dc.date.issued	2023
dc.description.abstract	Magnetically induced ring currents are a conventional tool for the characterization of aromaticity. Dia- and paratropic currents are thought to be associated with stabilization (aromaticity) and destabilization (antiaromaticity), respectively. In the present work, I have questioned the validity of the paratropic currents as a measure of antiaromaticity among monocyclic hydrocarbons. I have shown that while reduced/oxidized radical ions of hydrocarbons sustain strong paratropic currents, they often gain extra stabilization via cyclic conjugation compared to their acyclic counterparts.	en
dc.description.sponsorship	National Science Centre,Poland 2020/39/B/ST4/02022 ; Poland’s High-Performance Computing Infrastructure PLGrid (HPC Centers: ACK Cyfronet AGH) grant no.PLG/2022/016057
dc.identifier.citation	J. Org. Chem. 2023 ; https://doi.org/10.1021/acs.joc.3c01807	en
dc.identifier.doi	10.1021/acs.joc.3c01807
dc.identifier.issn	0022-3263
dc.identifier.issn	1520-6904
dc.identifier.uri	https://open.icm.edu.pl/handle/123456789/22935
dc.language.iso	en
dc.publisher	ACS Publications	en
dc.rights	Uznanie autorstwa 4.0 Międzynarodowe	*
dc.rights.uri	http://creativecommons.org/licenses/by/4.0/	*
dc.title	Magnetic Antiaromaticity─Paratropicity─Does Not Necessarily Imply Instability	en
dc.type	article	en