Reductive Elimination from Sterically Encumbered Ni−Polypyridine Complexes

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dc.contributor.authorDay, Craig S.
dc.contributor.authorTon, Stephanie J.
dc.contributor.authorMcGuire, Ryan T.
dc.contributor.authorForoutan-Nejad, Cina
dc.contributor.authorMartin, Ruben
dc.contributor.organizationBarcelona Institute of Science and Technology, Institute of Chemical Research of Cataloniaen
dc.contributor.organizationDepartament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, Spainen
dc.contributor.organizationInstitute of Organic Chemistry, Polish Academy of Sciencesen
dc.date.accessioned2022-11-02T15:46:38Z
dc.date.available2022-11-02T15:46:38Z
dc.date.issued2022
dc.description.abstractHerein we disclose the synthesis of sterically encumbered dialkylnickel(II) complexes bearing 2,9-dimethyl-1,10-phenanthroline ligands. A comparison with their unsubstituted analogues by both X-ray crystallography and theoretical calculations revealed significant distortions in their molecular structures. Eyring plots along with stoichiometric and photoexcitation studies revealed that sterically encumbered dialkylnickel(II) complexes enable facile C(sp3)–C(sp3) reductive elimination, thus offering an improved understanding of Ni catalysis.en
dc.description.sponsorshipICIQ and MICIU (PID2021-133801NB-I00) European Union’s Horizon 2020 Programme under Marie Curie PREBIST Grant Agreement 754558 National Science Centre, Poland (2020/39/B/ST4/02022)
dc.identifier.citationOrganometallics 2022, 41, 2662−2667 ; https://doi.org/10.1021/acs.organomet.2c00362en
dc.identifier.doi10.1021/acs.organomet.2c00362
dc.identifier.issn0276-7333
dc.identifier.urihttps://open.icm.edu.pl/handle/123456789/21811
dc.language.isoen
dc.publisherAmerican Chemical Societyen
dc.rightsUznanie autorstwa 4.0 Międzynarodowe*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.titleReductive Elimination from Sterically Encumbered Ni−Polypyridine Complexesen
dc.typearticleen
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