Steady-state thermodynamics of a system with heat and mass flow coupling
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42.Steady-state thermodynamics_R.Holyst.pdf (4.41 MB)
0000-0002-9769-7646 Date
2023
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AIP Publishing
Abstract
Equilibrium thermodynamics describes the energy exchange of a body with its environment. Here, we describe the global energy exchange of an ideal gas in the Coutte flow in a thermodynamic-like manner. We derive a fundamental relation between internal energy as a function of parameters of state. We analyze a non-equilibrium transition in the system and postulate the extremum principle, which determines stable steady states in the system. The steady-state thermodynamic framework resembles equilibrium thermodynamics.
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Citation
J. Chem. Phys. 159, 194113 (2023). https://doi.org/10.1063/5.0170079